Radioactivity
In 1896, Henri Becquerel was working with compounds containing the element uranium. To his surprise, he found that photographic plates covered to keep out light became fogged, or partially exposed, when these uranium compounds were anywhere near the plates. This fogging suggested that some kind of ray had passed through the plate coverings. Several materials other than uranium were also found to emit these penetrating rays. Materials that emit this kind of radiation are said to be radioactive and to undergo radioactive decay.
In 1899, Ernest Rutherford discovered that uranium compounds produce three different kinds of radiation. He separated the radiations according to their penetrating abilities and named them a alpha, b beta, and g gamma radiation, after the first three letters of the Greek alphabet. The a radiation can be stopped by a sheet of paper. Rutherford later showed that an alpha particle is the nucleus of a He atom, 4He. Beta particles were later identified as high speed electrons. Six millimeters of aluminum are needed to stop most b particles. Several millimeters of lead are needed to stop g rays , which proved to be high energy photons. Alpha particles and g rays are emitted with a specific energy that depends on the radioactive isotope. Beta particles, however, are emitted with a continuous range of energies from zero up to the maximum allowed for by the particular isotope.
? decay
The emission of an a particle, or 4He nucleus, is a process called a decay. Since a particles contain protons and neutrons, they must come from the nucleus of an atom. The nucleus that results from a decay will have a mass and charge different from those of the original nucleus. A change in nuclear charge means that the element has been changed into a different element. Only through such radioactive decays or nuclear reactions can transmutation, the age-old dream of the alchemists, actually occur. The mass number, A, of an a particle is four, so the mass number, A, of the decaying nucleus is reduced by four. The atomic number, Z, of 4He is two, and therefore the atomic number of the nucleus, the number of protons, is reduced by two. This can be written as an equation analogous to a chemical reaction. For example, for the decay of an isotope of the element seaborgium, 263Sg:
The atomic number of the nucleus changes from 106 to 104, giving rutherfordium an atomic mass of 263-4=259. a decay typically occurs in heavy nuclei where the electrostatic repulsion between the protons in the nucleus is large. Energy is released in the process of a decay. Careful measurements show that the sum of the masses of the daughter nucleus and the a particle is a bit less than the mass of the parent isotope. Einstein’s famous equation, E=mc2, which says that mass is proportional to energy, explains this fact by saying that the mass that is lost in such decay is converted into the kinetic energy carried away by the decay products.
? Decay
Beta particles are negatively charged electrons emitted by the nucleus. Since the mass of an electron is a tiny fraction of an atomic mass unit, the mass of a nucleus that undergoes b decay is changed by only a tiny amount. The mass number is unchanged. The nucleus contains no electrons. Rather, b decay occurs when a neutron is changed into a proton within the nucleus. An unseen neutrino,
, accompanies each b decay. The number of protons, and thus the atomic number, is increased by one. For example, the isotope 14C is unstable and emits a ? particle, becoming the stable isotope 14N:
In a stable nucleus, the neutron does not decay. A free neutron, or one bound in a nucleus that has an excess of neutrons, can decay by emitting a b particle. Sharing the energy with the b particle is a neutrino. The neutrino has little or no mass and is uncharged, but, like the photon, it carries momentum and energy. The source of the energy released in b decay is explained by the fact that the mass of the parent isotope is larger than the sum of the masses of the decay products. Mass is converted into energy just as Einstein predicted.
? Decay
Gamma rays are a type of electromagnetic radiation that results from a redistribution of electric charge within a nucleus. A g ray is a high energy photon. The only thing which distinguishes a g ray from the visible photons emitted by a light bulb is its wavelength; the g ray’s wavelength is much shorter. For complex nuclei there are many different possible ways in which the neutrons and protons can be arranged within the nucleus. Gamma rays can be emitted when a nucleus undergoes a transition from one such configuration to another. For example, this can occur when the shape of the nucleus undergoes a change. Neither the mass number nor the atomic number is changed when a nucleus emits a g ray in the reaction
The time required for half of the atoms in any given quantity of a radioactive isotope to decay is the half-life of that isotope. Each particular isotope has its own half-life. For example, the half-life of 238U is 4.5 billion years. That is, in 4.5 billion years, half of the 238U on Earth will have decayed into other elements. In another 4.5 billion years, half of the remaining 238U will have decayed. One fourth of the original material will remain on Earth after 9 billion years. The half-life of 14C is 5730 years, thus it is useful for dating archaeological material. Nuclear half-lives range from tiny fractions of a second to many, many times the age of the universe.
For more information on half-life and isotopes, please refer to the Isotopes Project at LBNL where you can also find the Table of Isotopes online.
